From the data above, the energy required to break four carbon-hydrogen bonds = 170.9 + (4 × 52.1) + 17.9 = 397.2 kcal. The carbon-hydrogen bond energy = 397.2/4 ≈ 99 kcal.
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C-H bond dissociation energy.
C(s) → C(g) ΔHC = 170.9 kcal
CH4 → C (s) + 4 H (g) ΔH = 397.2 kcal
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Bond Dissociation Energy – Definition, Formula, Calculation
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As an example of bond dissociation enthalpy, to break 1 mole of gaseous hydrogen chloride molecules into separate gaseous hydrogen and chlorine atoms requires 432 kJ. The bond dissociation enthalpy for the H-Cl bond is +432 kJ mol–1.
Bind enthalpy (also known as bond dissociation enthalpy, average bond energy, or bond strength) describes the amount of energy stored in a bond between atoms in a molecule. Specifically, it is the energy that must be supplied for the homolytic or symmetric cleavage of a bond in the gas phase.
To calculate an energy change for a reaction: add the binding energies for all bonds in the reactants – this is the “energy in” add the bond energies for all bonds in the products – this is the “energy”. out’ Energy change = Energy in – Energy out.
The key difference between bond dissociation energy and bond energy is that bond energy is the average amount of energy required to break all bonds in a compound between the same two types of atoms whereas bond dissociation energy is the amount of energy required to homolytically break a given bond.. .
The homolytic bond dissociation energy is the amount of energy required to split one mole of covalently bound gases into a pair of radicals. The SI units used to describe binding energy are kilojoules per mole of binding (kJ/mole). It indicates how strongly the atoms are bound to each other.
113.45 Kcal/mol for the binding energy of H20.
Therefore the order for the bond dissociation enthalpy of halogen molecules is $C{l_2} > B{r_2} > {F_2} > {I_2}$, indicating option B as the correct choice.
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